If you want to prevent that number from being able to call your Samsung GT-S5360, you can add a number to your ‘Reject List’.
To add a number to the Reject List , you just need to follow the instructions:
Go to your Samsung GT-S5360
Open the contact page
Select number from the list
Press Menu key
Add to reject list.
Please note that in your Samsung GT-S5360, the Reject List just can block calls from the blocked numbers which are shown with the common blue No symbol
Another method you maybe like:
You also can use Third-party apps for blocking phone calls in the Samsung GT-S5360.
This application both blocks calls and SMS which are unwanted, and can help manage a blacklist. It is so easy and lightweight, and does not consume any of your device’s battery power.